Dependence of the liquid-vapor surface tension on the range of interaction: a test of the law of corresponding states.

Long Range Corrections to the Vapor-Liquid Equilibrium and Surface Tension of Methane with NVT Molecular Dynamics Simulations

Density and Temperature Dependencies of Liquid Surface Tension

In this paper the density and temperature dependencies of surface tension are investigated. Using the Lennard-Jones (12,6), as an effective pair interaction potential, a linear expression is derived for isotherms of g /r2  versus r2 for some normal and ChloroFluoroCarbons (CFCs)</...

THE EXTENDED LAW OF CORRESPONDING - STATES AND THE INTERMOLECULAR POTENTIALS FOR Ar-Ar, Ar-Kr AND Kr-Kr

An inversion procedure is used to obtain from the extended principle of corresponding - states the pair interaction potentials for argon, krypton and its mixture over a tetnperature range from absolute zero to the onset of ionization. The experimentally-reduced viscosity collision integrals obtained from the corresponding - states correlation have been inverted directly to give the reduced...

A New Surface Tension Model for Prediction of Interaction Energy between Components and Activity Coefficients in Binary Systems

In this work, we develop a correlative model based on the surface tension data in order to calculate thermodynamic parameters, such as interaction energy between components (Uij), activity coefficients and etc. In the new approach, by using Li et al. (LWW) model, a three-parameter surface tension equation is derived for liquid mixtures. The surface tension data of 54 aqueous and 73 non-aqueous ...

Pressure Dependence of Liquid Vapor Pressure: An Improved Gibbs Prediction

A new model for the vapor phase of a pressurized liquid called "the cluster model: which is originally introduced in this work, along with an accurate equation of state for the liquid phase called the LIR, is used to derive an accurate equation for the vapor pressure of liquid as a function of external pressure. The chemical Potential of both phase have been found to be in good agreement wi...